Date: Tue, 02 Dec 1997 03:07:41 +0200
From: Durk Ellison
Subject: Propolis
EIGHT INTERNATIONAL SYMPOSIUM ON TRENDS
IN BIOMEDICINE IN FINLAND: ALLERGY, OXIDANTS AND
ANTIOXIDANTS, AND HUMAN HEALTH
Orion, Orionint. 1, Espoo, Finland
14.11.97
ABSTRACTS & ESSAYS
ARRANGED BY THE FINNISH SOCIETY FOR BIOLOGICAL MEDICINE

The Ability of bee products to modulate human immuno system

L Mackevicius, L.R. Cerniauskiene, D. Reingardiene,
R. Preiksa. Z. Varskeviviene. L. Berontiene, L. Margeviciene
Kaunas Medical Academy Kaunas Academiy Clinics
Leiveniu St.2
Institute of Cardiology
Sukiteliu St. 17
3007 Kaunas
Lithuania

The human body is constantly under attack of free radicals. Free radicals are highly reactive molecules by the biochemical redox reactions that occur as part of normal metabolism and by exposure to environmental factors such as u.v. light, cigarette smoke,environmental pollutants and gamma radiation. Once formed, free radicals attack cell structures within the body. As a result, free radicals have been implicated in numerous diseases examples of which are listed below: Cancer, atheroscleroses rheumatoid arthritis, diabetes, cataracts conditions associated with premature birth, motor neurone disease, liver damage, respiratory disease, central nervous system disorders.

In healthy individuals, the antioxidant system defends tissues against free radical attack; three classes of antioxidant defend the body against free radical attack. Primary antioxidants - superoxide dismutase, glutathione peroxidase, cacruloplasmin prevent the formation of new free radical species. Secondary antioxidants - vitamin E, vitamin C, B carotine, uric acid, bilirubin and albumin trap newly formed free radicals before they can initiate chain reactions leading to cell damage and further free radical formation. Tertiary antioxidants - DNA repair enzymes. Methionine sulphoxidereductase repair cell structures damaged by free radical attack. Deficiencies in the antioxidant system can develop for a number of reasons low intake of dietary antioxidants, diseases that reduce the absorption of antioxidant nutrients from food (Crohn's Disease), total parenteral nutrition renal dialysis.

In these situations the antioxidant system struggles to protect the body from free radical attack and as a result the risk of free radical-mediated disease increases. It is also known that bee venom, honey, royal jelly, pollen, bee bread are also antioxidantic products and can be used by patients treated by HBO.

PROPOLIS Propolis is a natural substance collected by honey bees from buds and trees. Propolis contains tree resin, essential oils, waxes and bioflavonoids. Biofiavonoids are one of the most important components in propolis; the antioxidant effects of bioflavonoids help maintain a healthy system.

The results achieved in Kaunas Academical hospital and in some other hospitals are presented here:

Qualitative compositon of propolis:
* Flavonoids
* Chalcones, Dihydrochalcones
* Aliphatic acid and their esters
* Long chain aliphatic acids
* Esters of some short chain volatile oils
* Aromatic acids and their esters
* Benzoic acid and derivatives
* Aldehyds
* Alcohols
* Cinnamic acid and its derivatives
* Other acid and derivatives
* Ketones, phenols and heteroaromatic compounds
* Terpene, sesquiterpene alcohols and their derivatives
* Terpenoids and other compounds
* Sesquiterpenes and triterpene hydrocarbons
* Volatile compounds
* Hydrocarbons
* Alifhatic hydrocarbons
* Sterols and steroid hydrocarbons
* Sugar
* Lactones
* Alfa and Beta- amilass
* Amino acids
* Derivatives of nucleic acids
* Vitamins
* Minerals
* Anaerobic Transhydrogenases
* Other substances
* Insoluble in water and organic solvents part
* Pollutants

Propolis contains about:

* 55% resins and balsams
* 7,5%-35% waxes
* 10% volatile oils
* 5% pollen
* 5% fatty acids
* 4,4%-195 impurities
* terpenes
* tannin substances, salivary gland secretion of the bees and accidental compounds

Flavones:
* acacetin
* chrysin
* tectochrysin
* apigenin
* pectolinaringenin
Flavonol

* galangin
* Galangin- 3-methyl ether
* isalpinin
* kaempferide
* kaemferol
* quecetin
* quercetin-3,3-dimethylether
* rhamnocitrin
* rhamnetin
* isorhamnetin

Lavonones:

* pinostrobin
* sakuranetin

Lavononols:

* pinobanksin etc.

An antioxidantic action of propolis has been an object of several studies. The aim of this study is to investigate the action of propolis on lipid peroxidation level in blood lipoproteins in vitro.

Methods. Free radical generation marker thiobarbituric acid reactive materials (TBARM) was measured by fluorimetrical method in blood serum lipoproteins samples after their 20 min. Incubation with propolis (0,2 ml of 0,2%, 1%, and 2% athanolic solution). MDA concentration was measured in samples after incubation by fluorimetrical method (K. Yagi, 1976). Fluorescence intensity was measured at 515nm, using "Hitachi" spectrofluorimeter. In serum samples, incubated with 0,2%. propolis, MDA concentration was significantly lower than in control samples (Figure). In samples, incubated with 1 and 2 % propolis, MDA concentration was higher than in control sample: in samples,incubated with 20%. propolis, MDA concentration was significantly higher than in control samples(p<0.05).

VITAMINS

B1, B2, B6, C, E nicotinic acid, panthothenic acid A
The vitamins in propolis are in very small amounts being related mainly to the pollen content.

MINERALS

Sodium (Na), potassium (K), magnesium (Mg), calcium (Ca), barium (Ba), boron (B) (traces), strontium (Sr), zinc (Zn), cadium (Cd), aluminium silicon (Si), lead (Pb),selenium (Se) (traces), iron (Fe), nickel (Ni),chromium (Cr), manganese (Mn), titanium (Ti), silver (Ag), copper (Cu),cobalt (CO), molybdenum (Mo), vanadium(V)

(FIGURE)

Figure. Malondialdegyde production in blood serum samples (from four donors), incubated 20 min. with ethanol solution of propolis ( 0,1 and 2%). Malondialdehyde level was expressed as percentage deviation from its level in control samples, incubated with ethanol.

Regards from:
Durk Ellison
Vantaa, Finland
BeeNet : 240:346/300.8
e-mail : Durk.Ellison@beenet.pp.sci.fi
Packet : oh2zas @ oh2rbt.#hki.fin.eu


Created: 12/2/97